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Tokyo Institute of Technology

OTSUKA LABORATORY

研究業績ACHIEVEMENT

     

論文 -ORIGINAL PAPER-

     

著書 -BOOK-

     

総説・解説 -REVIEW-

     
     

論文 -ORIGINAL PAPER-


122. Thermally Healable and Reprocessable Bis(hindered amino)disulfide-Cross-Linked Polymethacrylate Networks
   A. TAKAHASHI, R. GOSEKI, K. ITOH, H. OTSUKA
   ACS Macro Lett. (2017).
   DOI: 未定

121. Tetraarylsuccinonitriles as Mechanochromophores to Generate Highly Stable Luminescent Carbon-Centered Radicals
   T. SUMI, R. GOSEKI, H. OTSUKA
  Chem. Commun. (2017).
   DOI: 10.1039/C7CC06913H

120. Photoregulation of Retro-Diels–Alder Reaction at the Center of Polymer Chains
   J. KIDA, K. IMATO, R. GOSEKI, M. MORIMOTO, H. OTSUKA
   Chem. Lett., 46, 992-994 (2017).
   DOI: org/10.1246/cl.170251

119. Dynamic covalent diarylbibenzofuranone-modified nanocellulose:
   Mechanochromic behaviour and application in self-healing polymer composites
   K. IMATO, J. C. NATTERODT, J. SAPKOTA, R. GOSEKI, C. WEDER, A. TAKAHARA, H. OTSUKA
   Polym. Chem., 8, 2115-2122 (2017).
   DOI: 10.1039/c7py00074j

118. A vinylic rotaxane cross-linker for toughened network polymers from the radical
   polymerization of vinyl monomers
   J. SAWADA, D. AOKI, M. KUZUME, K. NAKAZONO, H. OTSUKA, T. TAKATA
   Polym. Chem., 8, 1878-1881 (2017).
   DOI: 10.1039/c7py00193b

117. Synthesis of Rotaxane Cross-linked Polymers with Supramolecular Cross-linkers
   Based on γ-CD and PTHF Macromonomers: The Effect of the Macromonomer Structure
   on the Polymer Properties
   K. IIJIMA, D. AOKI, H. OTSUKA, T. TAKATA
   Polymer (2017), 128, 392-396 (2017).
   DOI: org/10.1246/cl.170251

116. Thermally Adjustable Dynamic Disulfide Linkages Mediated by Highly Air-Stable
   2,2,6,6-Tetramethylpiperidine-1-sulfanyl (TEMPS) Radicals (Accepted Frontispiece)
   A. TAKAHASHI, R. GOSEKI, H. OTSUKA
   Angew. Chem. Int. Ed. 56, 2016-2021 (2017).
   DOI: 10.1002/anie.201611049

115. Enhancing Mechanochemical Activation in the Bulk State by Designing Polymer Architectures
   H. OKA, K. IMATO, T. SATO, T. OHISHI, R. GOSEKI, H. OTSUKA
   ACS Macro Lett., 5, 1124-1127 (2016).
   DOI: 10.1021/acsmacrolett.6b00529

114. Polymer-Inorganic Composites with Dynamic Covalent Mechanochromophore
   T. KOSUGE, K. IMATO, R. GOSEKI, H. OTSUKA
   Macromolecules, 49, 5903-5911 (2016).
   DOI: 10.1021/acs.macromol.6b01333

113. Repeatable Mechanochemical Activation of Dynamic Covalent Bonds in Thermoplastic Elastomers
   K. IMATO, T. KANEHARA, S. NOJIMA, T. OHISHI, Y. HIGAKI, A. TAKAHARA, H. OTSUKA
   Chem. Commun., 52, 10482-10485 (2016).
   DOI: 10.1039/c6cc04767j

112. Facile Modification and Fixation of Diary Disulphide-containing Dynamic Covalent Polyesters by
   Iodine-catalysed Insertion-like Addition Reactions of Styrene Derivatives to Disulphide Units
   Y. NAKAI, A. TAKAHASHI, R. GOSEKI, H. OTSUKA
   Polym. Chem., 7, 4661-4666 (2016).
   DOI: 10.1039/c6py00963h

111. Triggered Structural Control of Dynamic Covalent Aromatic Polyamides: Effects of Thermal
   Reorganization Behavior in Solution and Solid States
   M. AIBA, T. HIGASHIHARA, M. ASHIZAWA, H. OTSUKA, H. MATSUMOTO
   Macromolecules, 49, 2153-2161 (2016).
   DOI: 10.1021/acs.macromol.5b01778

110. Degradable Epoxy Resins Prepared from Diepoxide Monomer with Dynamic Covalent Disulfide Linkage
   A. TAKAHASHI, T. OHISHI, R. GOSEKI, H. OTSUKA
   Polymer, 82 319-326 (2016).
   DOI: 10.1016/j.polymer.2015.11.057

109. Autonomously Substitutable Organosilane Thin Films Based on Dynamic Covalent Diarylbibenzofuranone
   Units
   R. YONEYAMA, T. SATO, K. IMATO, T. KOSUGE, T. OHISHI, Y. HIGAKI, A. TAKAHARA, H. OTSUKA
  Chem. Lett., 45, 36-38 (2016).
  DOI: 10.1246/cl.150917
    
108. Radical Crossover Reactions of Alkoxyamine-Based Dynamic Covalent Polymer Brushes on Nanoparticles
   and the Effect on Their Dispersibility
   T. SATO, T. OHISHI, Y. HIGAKI, A. TAKAHARA, H. OTSUKA
   Polym. J., 48, 147-155 (2016).
   DOI: 10.1038/pj.2015.94

107. Mechanochromic Dynamic Covalent Elastomers: Quantitative Stress Evaluation and Autonomous
  Recovery
   K. IMATO, T. KANEHARA, T. OHISHI, M. NISHIHARA, H. YAJIMA, M. ITO, A. TAKAHARA, H. OTSUKA
   ACS Macro Lett., 4, 1307-1311 (2015).
   DOI: 10.1021/acsmacrolett.5b00717

106. Metathesis-driven Scrambling Reactions between Polybutadiene or Naturally Occurring Polyisoprene and
   Olefin-containing Polyurethane
   T. OHISHI, K. SUYAMA, S. KAMIMURA, M. SAKADA, K. IMATO, S. KAWAHARA, A. TAKAHARA,
   H. OTSUKA
   Polymer, 78, 145-153 (2015).
   DOI: 10.1016/j.polymer.2015.09.076

105. Self-Healing of a Cross-Linked Polymer with Dynamic Covalent Linkages at Mild Temperature and
   Evaluation at Macroscopic and Molecular Levels
  K. IMATO, A. TAKAHARA, H. OTSUKA
  Macromolecules, 48, 5632-5639 (2015).
  DOI: 10.1021/acs.macromol.5b00809

104. Diarylbibenzofuranone-Based Dynamic Covalent Polymer Gels Prepared via Radical Polymerization and
   Subsequent Polymer Reaction
  K. IMATO, N. NISHIHARA, A. IRIE, A. TAKAHARA, H. OTSUKA
  Gels, 4, 598-601 (2015).
  DOI: 10.3390/gels1010058

103. Synthesis of Vinylic Macromolecular Rotaxane Cross-Linkers Endowing Network Polymers
   with Toughness
  J. SAWADA, D. AOKI, S. UCHIDA, H.OTSUKA, T. TAKATA
  ACS Macro Lett., 4, 598-601 (2015).
  DOI: 10.1021/acsmacrolett.5b00242

102. Mechanophores with a Reversible Radical System and Freezing-Induced Mechanochemistry in Polymer
  Solutions and Gels
  K. IMATO, A. IRIE, T. KOSUGE, T. OHISHI, A. TAKAHARA, H. OTSUKA
  Angew. Chem. Int. Ed., 54, 6168-6172 (2015).
  DOI: 10.1002/anie.201412413

101. Polyurethane Nanocomposites Reinforced with Surface Modified Halloysite Nanotubes
  H. JING, Y. HIGAKI, T. ISHIKAWA, K. L. WHITE, H. OTSUKA, A. TAKAHARA
  Sci. Adv. Mater., 7, 974-980 (2015)
  DOI: 10.1166/sam.2015.2040

100. Synthesis of Polyethylene/polyester Copolymers through Main Chain Exchange Reactions via Olefin
  Metathesis
  T. MAEDA, S. KAMIMURA, T. OHISHI, A. TAKAHARA, H. OTSUKA
  Polymer, 55, 6245-6251 (2014)
  DOI: 10.1016/j.polymer.2014.10.001

99. Network Reorganization of Dynamic Covalent Polymer Gels with Exchangeable Diarylbibenzofuranone at
  Ambient Temperature
  K. IMATO, T. OHISHI, M. NISHIHARA, A. TAKAHARA, H. OTSUKA
  J. Am. Chem. Soc, 136, 11839-11845 (2014)
  DOI: 10.1021/ja5065075

98. Plasticizer-Promoted Thermal Cross-linking of a Dynamic Covalent Polymer with Complementarily
  Reactive Alkoxyamine Units in the Side Chain under Bulk Conditions
  J. SU, K. IMATO, T. SATO, T. OHISHI, A. TAKAHARA, H. OTSUKA
  Bull. Chem. Soc. Jpn., 87, 1023-1025 (2014)
  DOI: 10.1246/bcsj.20140147

97. Radical Crossover Reactions of a Dynamic Covalent Polymer Brush for Reversible Hydrophilicity Control
  T. SATO, Y. AMAMOTO, T. OHISHI, Y. HIGAKI, A. TAKAHARA, H. OTSUKA
  Polymer, 55, 4586-4592 (2014)
  DOI: 10.1016/j.polymer.2014.07.010

96. Preparation and Characterization of Polycarbonate Nanocomposites Based on Surface-modified Halloysite
  Nanotube
  H. JING, Y. HIGAKI, W. MA, J. XI, H. JINNAI, H. OTSUKA, A. TAKAHARA
  Polym. J., 46, 307-312 (2014)
  DOI: 10.1038/pj.2013.100

95. Reversible Cross-linking Reactions of Alkoxyamine-appended Polymers under Bulk Conditions for
  Transition between Flow and Rubber-like State
  J. SU, Y. AMAMOTO, T. SATO, M. KUME, T. INADA, T. OHISHI, Y. HIGAKI, A. TAKAHARA, H. OTSUKA
  Polymer, 55, 1474-1480 (2014)
  DOI: 10.1016/j.polymer.2014.01.055

94. Insertion Metathesis Depolymerization of Aromatic-Disulfide-Containing Dynamic Covalent Polymers
  under Weak Intensity Photoirradiation
  T. OHISHI, Y. IKI, K. IMATO, Y. HIGAKI, A. TAKAHARA, H. OTSUKA
  Chem. Lett., 42, 1346-1348 (2013)
  DOI: 10.1246/cl.130639

93. Reversibly Cross-linked Polymeric Micelles Formed by Autonomously Exchangeable Dynamic Covalent
  Bonds
  M. NISHIHARA, K. IMATO, A. IRIE, T. KANEHARA, A. KANO, A.MARUYAMA, A. TAKAHARA, H. OTSUKA
  Chem. Lett., 42, 377-379 (2013)
  DOI: 10.1246/cl.121289

92. Internally Modified Halloysite Nanotubes as Inorganic Nanocontainers for a Flame Retardant
  H. JING, Y HIGAKI, W. MA, H. WU, W. O. YAH, H. OTSUKA, Y. LVOV, A. TAKAHARA
  Chem. Lett., 42, 121-123 (2013)
  DOI: 10.1246/cl.2013.1211

91. Preparation of novel polyimide hybrid materials by multi-layered charge-transfer complex formation
  R. WATARI, M. NISHIHARA, H. TAJIRI, H. OTSUKA, A. TAKAHARA
  Polym. J., 45, 839-844 (2013)
  DOI: 10.1038/pj.2012.222

90. Structural Effects of Catechol-Containing Polystyrene Gels Based on Dual Cross-linking Approach
  H. XU, J. NISHIDA, H. WU, Y. HIGAKI, H. OTSUKA, N. OHTA, A. TAKAHARA
  Soft Matter, 9, 1967-1974 (2013)
  DOI: 10.1039/C2SM26994E

89. Perfluoropolyether-infused Nano-texture: A Versatile Approach to Omniphobic Coatings with Low
  Hysteresis and High Transparency
  W. MA, Y. HIGAKI, H. OTSUKA, A. TAKAHARA
  Chem. Commun., 49, 597-599 (2013)
  DOI: 10.1039/c2cc37576a

88. Dynamic Covalent Polymer Brushes: Reversible Surface Modification of Reactive Polymer Brushes with
  Alkoxyamine-based Dynamic Covalent Bonds
  T. SATO, Y. AMAMOTO, H. YAMAGUCHI, T. OHISHI, A. TAKAHARA, H. OTSUKA
  Polym. Chem., 3, 3077-3083, (2012)
  DOI: 10.1039/C2PY20294H

87. Self-Healing of Covalently Cross-Linked Polymers by Reshuffling Thiuram Disulfide Moieties in Air under
  Visible Light
  Y. AMAMOTO, H. OTSUKA, A. TAKAHARA, and K. MATYJASZEWSKI
  Adv. Mater., 24,3975-3980, (2012)
  DOI: 10.1002/adma.201201928

86. “Non-sticky” superhydrophobic surface by self-assembly of fluoroalkyl phosphonic acid on a hierarchically
  micro/nanostructured alumina gel film
  W. MA, H. WU, Y. HIGAKI, H. OTSUKA, A. TAKAHARA
  Chem. Commun., 48, 6824-6826,(2012)
  DOI: 10.1039/C2CC32513F

85. Changes in Network Structure of Chemical Gels Controlled by Solvent Quality through Photoinduced
  Radical Reshuffling Reactions of Trithiocarbonate Units
  Y. AMAMOTO, H. OTSUKA, A. TAKAHARA, K. MATYJASZEWSKI
  ACS Macro Lett., 1, pp478-481, (2012)
  DOI: 10.1021/mz300070t

84. Competition between Oxidation and Coordination in Cross-linking of Polystyrene Copolymer Containing
  Catechol Groups
  H. XU, J. NISHIDA, W. MA, H. WU, M. KOBAYASHI, H. OTSUKA, A. TAKAHARA
  ACS Macro Lett., 1, pp457-460, (2012)
  DOI: 10.1021/mz200217d

83. Preparation and Characterization of Imogolite/DNA Hybrid Hydrogels
  N. JIRAVANICHANUN, K. YAMAMOTO, K. KATO, J. KIM, S. HORIUCHI, W. O. YAH H. OTSUKA,
  A. TAKAHARA
  Biomacromolecules, Vol. 13, pp276-281 (2012)
  DOI: 10.1021/bm201616m

82. Self-healing of Chemical Gels Cross-linked by Diarylbibenzofuranone-based Trigger-free Dynamic
  Covalent Bonds at Room Temperature
  K. IMATO, M. NISHIHARA, T. KANEHARA, Y. AMAMOTO, A. TAKAHARA, H. OTSUKA
  Angew. Chem. Int. Ed., Vol. 51, pp1138-1142 (2012)
  DOI: 10.1002/anie.201104069

81. Preparation and Properties of PVC/PMMA-g-imogolite Nanohybrid via Surface-Initiated Radical
  Polymerization
  W. MA, H. OTSUKA, A. TAKAHARA
  Polymer, Vol. 52, pp5543-5550 (2011)
  DOI: 10.1016/j.polymer.2011.09.054

80. Reversible Cross-linking of Hydrophilic Dynamic Covalent Polymers with Radically Exchangeable
  Alkoxyamines in Aqueous Media
  S. JING, Y. AMAMOTO, M. NISHIHARA, A. TAKAHARA, H. OTSUKA
  Polym. Chem., Vol. 2, pp2021-2026 (2011)
  DOI: 10.1039/C1PY00176K

79. Molecular Aggregation State and Electrical Properties of Terthiophenes/Imogolite Nanohybrids
  W. O. YAH, A. IRIE, N. JIRAVANICHANUN, H. OTSUKA, A. TAKAHARA
  Bull. Chem. Soc. Jpn., Vol. 84, pp893-902 (2011)
  DOI: 10.1246/bcsj.20110080

78. Poly(methyl methacrylate) Grafted Imogolite Nanotubes Prepared through Surface-initiated ARGET ATRP
  W. MA, H. OTSUKA, A. TAKAHARA
  Chem. Commun., Vol. 47, pp5813-5815 (2011)
  DOI: 10.1039/C1CC10661A

77. Preparation of Superparamagnetic β-Cyclodextrin-functionalized Composite Nanoparticles with Core-shell
  Structures
  R.-X. LI, S.-M. LIU, J.-Q. ZHAO, H. OTSUKA, A. TAKAHARA
  Polym. Bull., Vol. 66, pp1125-1136 (2011)
  DOI: 10.1007/s00289-010-0410-y

76. Preparation and Characterization of Cross-linked Beta-cyclodextrin Polymer/Fe3O4 Composite
  Nanoparticles with Core-shell Structures
  R.-X. LI, S.-M. LIU, J.-Q. ZHAO, H. OTSUKA, A. TAKAHARA
  Chinese Chem. Lett., Vol. 22, pp217-220 (2011)
  DOI: 10.1016/j.cclet.2010.09.014

75. Surface Modification of Individual Imogolite Nanotubes with Alkyl Phosphate from an Aqueous Solution
  W. MA, J. KIM, H. OTSUKA, A. TAKAHARA
  Chem. Lett., Vol. 40, pp159-161 (2011)
  DOI: 10.1246/cl.2011.159

74. Mesh-Size Control and Functionalization of Reorganizable Chemical Gels by Monomer Insertion into
  Their Cross-Linking Points
  Y. AMAMOTO, M. KIKUCHI, H. MASUNAGA, H. OGAWA, S. SASAKI, H. OTSUKA, A. TAKAHARA
  Polym. Chem., Vol. 2, pp957-962 (2011)
  DOI: 10.1039/C0PY00304B

73. Repeatable Photoinduced Self-Healing of Covalently Cross-Linked Polymers through Reshuffling of
  Trithiocarbonate Units
  Y. AMAMOTO, J. KAMADA, H. OTSUKA, A. TAKAHARA, K. MATYJASZEWSKI
  Angew. Chem. Int. Ed., Vol. 50, pp1660-1663 (2011)
  DOI: 10.1002/anie.201003888

72. “Substitutable” Polymer Brushes: Reactive Poly(methacrylate) Brushes with Exchangeable Alkoxyamine
  Units in the Side Chain
  T. SATO, Y. AMAMOTO, H. YAMAGUCHI, H. OTSUKA, A. TAKAHARA
  Chem. Lett., Vol. 39, pp1209-1211 (2010)
  DOI: 10.1246/cl.2010.1209

71. Arm-replaceable Star-like Nanogels: Arm Detachment and Arm Exchange Reactions by Dynamic Covalent
  Exchanges of Alkoxyamine Units
  Y. AMAMOTO, M. KIKUCHI, H. OTSUKA, A. TAKAHARA
  Polym. J., Vol. 42, pp860-867 (2010)
  DOI: 10.1038/pj.2010.83

70. Influence of Magadiite Dispersion States on the Flammability of Polystyrene and Polyphenylene
  Ether-Polystyrene Alloy Nanocomposites
  H. YUKUTAKE, M. KOBAYASHI, H. OTSUKA, A. TAKAHARA
  Polym. J., Vol. 42, pp223-231 (2010)
  DOI: 10.1038/pj.2009.336

69. Solvent-Controlled Formation of Star-like Nanogels via Dynamic Covalent Exchange of PSt-b-PMMA
  Diblock Copolymers with Alkoxyamine Units in the Side Chain
  Y. AMAMOTO, M. KIKUCHI, H. OTSUKA, A. TAKAHARA
  Macromolecules, Vol. 43, pp5470-5473 (2010)
  DOI: 10.1021/ma100276n

68. Intelligent Build-Up of Complementarily Reactive Diblock Copolymers via Dynamic Covalent Exchange
  toward Symmetrical and Miktoarm Star-like Nanogels
  Y. AMAMOTO, M. KIKUCHI, H. MATSUNAGA, S. SASAKI, H. OTSUKA, A. TAKAHARA
  Macromolecules, Vol. 43, pp1785-1791 (2010)
  DOI: 10.1021/ma030115y

67. A Dynamic Covalent Polymer Driven by Disulfide Metathesis under Photoirradiation
  H. OTSUKA, S. NAGANO, Y. KOBASHI, T. MAEDA, A. TAKAHARA
  Chem. Commun., Vol. 46, pp1150-1152 (2010)
  DOI: 10.1039/B916128G

66. Reorganizable Chemical Polymer Gels Based on Dynamic Covalent Exchange and Controlled Monomer
  Insertion
  Y. AMAMOTO, M. KIKUCHI, H. MATSUNAGA, S. SASAKI, H. OTSUKA, A. TAKAHARA
  Macromolecules, Vol. 42, pp8733-8738 (2009)
  DOI: 10.1021/ma901746n

65. Molecular Aggregation State and Photovoltaic Properties of Chlorophyll-Doped Conducting
  Poly(3-hexylthiophene)/MCM-41 Nanocomposites
  W. O. YAH, Z. WANG, H. OTSUKA, K. KATO, J. KIM, M. TAKATA, A. TAKAHARA
  ACS Appl. Mater. Interfaces, Vol. 1, pp1544-1552 (2009)
  DOI: 10.1021/am9002099

64. Thermal Degradation Behavior of Polystyrene/magadiite Nanocomposites Prepared by Surface-initiate
  Nitroxide-mediated Radical Polymerization
  H. YUKUTAKE, M. KOBAYASHI, H. OTSUKA, A. TAKAHARA
  Polym. J., Vol. 41, pp555-561 (2009)
  DOI: 10.1295/polymj.PJ2009044

63. Scrambling Reaction between Polymers Prepared by Step-growth and Chain-growth Polymerizations:
  Macromolecular Cross-metathesis between 1,4-Polybutadiene and Olefin-containing Polyester
  H. OTSUKA, T. MUTA, M. SAKAD, T. MAEDA, A. TAKAHARA
  Chem. Commun., Vol. 45, pp1073-1074 (2009)
  DOI: 10.1039/B818014H

62. Rational Approach to Star-like Nanogels with Different Arm Lengths: Formation by Dynamic Covalent
  Exchange and Their Imaging
  Y. AMAMOTO, T. MAEDA, M. KIKUCHI, H. OTSUKA, A. TAKAHARA
  Chem. Commun., Vol. 45, pp689-691 (2009)
  DOI: 10.1039/B818049K

61. Fabrication of Conjugated Polymer Hybrid Thin Films with Radially Oriented Aluminosilicate Nanofibers by
  Spin-Assembly
  N. JIRAVANICHANUN, K. YAMAMOTO, H. YONEMURA, S. YAMADA, H. OTSUKA, A.TAKAHARA
  Bull. Chem. Soc. Jpn., Vol. 81, pp1663-1668 (2008)
  DOI: 10.1246/bcsj.81.1663

60. Control of Dispersion State of Silsesquioxane Nanofillers for Stabilization of Polystyrene Thin Films
  N. HOSAKA, N. TORIKAI, M. HINO, H. OTSUKA, A. TAKAHARA
  Langmuir, Vol. 24, pp5766-5772 (2008)
  DOI: 10.1021/la704062n

59. Dewetting Inhibition and Interfacial Structures of Silsesquioxane-terminated Polystyrene Thin Films
  K. MIYAMOTO, N. HOSAKA, M. KOBAYASHI, H. OTSUKA, N. YAMADA, N. TORIKAI A. TAKAHARA
  Polym. J., Vol. 39, pp1247-1252 (2007)
  DOI: 10.1295/polymj.PJ2007067

58. Programmed Thermodynamic Formation and Structure Analysis of Star-like Nanogels with Core
  Cross-linked by Thermally Exchangeable Dynamic Covalent Bonds
  Y. AMAMOTO, Y. HIGAKI, Y. MATSUDA, H. OTSUKA, A. TAKAHARA
  J. Am. Chem. Soc., Vol. 129, pp13298-13304 (2007)
  DOI: 10.1021/ja075447n

57. Programmed Formation of Nanogels via a Radical Crossover Reaction of Complementarily Reactive
  Diblock Copolymers
  Y. AMAMOTO, Y. HIGAKI, Y. MATSUDA, H. OTSUKA, A. TAKAHARA
  Chem. Lett., Vol. 36, pp774-775 (2007)
  DOI: 10.1246/cl.2007.774

56. Thermal Reorganization and Molecular Weight Control of Dynamic Covalent Polymers Containing
  Alkoxyamines in Their Main Chains
  H. OTSUKA, K. AOTANI, Y. HIGAKI, Y. AMAMOTO, A. TAKAHARA
  Macromolecules, Vol. 40, pp1429-1434 (2007)
  DOI: 10.1021/ma061667u

55. Structure and Dewetting Behavior of Polyhedral Oligomeric Silsesquioxane-Filled Polystyrene Thin Films
  N. HOSAKA, N. TORIKAI, H. OTSUKA, A. TAKAHARA
  Langmuir, Vol. 23, pp902-907 (2007)
  DOI: 10.1021/la062255h

54. Analysis of Molecular Aggregation States in Pentacene Thin Films Prepared from Soluble Precursor
  T. AKINAGA, S. YASUTAKE, S. SASAKI, O. SAKATA, H. OTSUKA, A. TAKAHARA
  Chem. Lett., Vol. 35, pp1162-1163 (2006)
  DOI: 10.1246/cl.2006.1162

53. Stabilization of Polystyrene Thin Films against Dewetting by Silsesquioxane-terminated Polystyrene
  Additives
  K. MIYAMOTO, N. HOSAKA, H. OTSUKA, A. TAKAHARA
  Chem. Lett., Vol. 35, pp1098-1099 (2006)
  DOI: 10.1246/cl.2006.1098

52. Facile Synthesis of Multiblock Copolymers Composed of Poly(tetramethylene oxide) and Polystyrene using
  Living Free-radical Polymerization Macroinitiator
  Y. HIGAKI, H. OTSUKA, A. TAKAHARA
  Polymer, Vol. 47, pp3784-3791 (2006)
  DOI: 10.1016/j.polymer.2006.03.100

51. Polystyrene-grafted Titanium Oxide Nanoparticles Prepared through Surface-initiated Nitroxide-mediated
  Radical Polymerization and Their Application to Polymer Hybrid Thin Films
  R. MATSUNO, H. OTSUKA, A. TAKAHARA
  Soft Matter, Vol. 2, pp415-421 (2006)
  DOI: 10.1039/B601197G

50. リジンイソシアナートを用いたセグメント化ポリウレタンウレアの特性解析と分解挙動
  波多野道子, 山口智弘, 大塚英幸、青井啓悟、佐々木園、高原 淳
  日本ゴム協会誌, Vol. 70, pp219-224 (2006)

49. A Thermodynamic Polymer Cross-linking System Based on Radically Exchangeable Covalent Bonds
  Y. HIGAKI, H. OTSUKA, A. TAKAHARA
  Macromolecules, Vol. 39, pp2121-2125 (2006)
  DOI: 10.1021/ma052093g

48. (Inorganic Nanofiber/Enzyme) Hybrid Hydrogel: Preparation, Characterization, and Enzyme Activity of
  Imogolite/Pepsin Conjugate
  N. INOUE, H. OTSUKA, S.-I. WADA, A. TAKAHARA
  Chem. Lett., Vol. 35, pp194-195 (2006)
  DOI: 10.1246/cl.2006.194

47. Preparation and Properties of [Poly(methyl methacrylate)/Imogolite] Hybrid via Surface Modification using
  Phosphoric Acid Ester
  K. YAMAMOTO, H. OTSUKA, S.-I. WADA, D. SOHN, A. TAKAHARA
  Polymer, Vol. 46, pp12386-12392 (2005)
  DOI: 10.1016/j.polymer.2005.10.108

46. Adsorbent for Di-n-butyl Phthalate using Chitosan Beads with Upper- or Lower-Rim Substituted
  Water-soluble Calixarenes
  A. YANAGI, H. OTSUKA, A. TAKAHARA
  Polym. J., Vol. 36, pp939-945 (2005)
  DOI: 10.1295/polymj.37.939

45. Tribological Properties of Poly(methyl methacrylate), Brushes Prepared by Surface-Initiated Atom
  Transfer Radical Polymerization
  H. SAKATA, M. KOBAYASHI, H. OTSUKA, A. TAKAHARA
  Polym. J., Vol. 36, pp765-775 (2005)
  DOI: 10.1295/polymj.37.767

44. Transparent Polymer Nanohybrid Prepared by in situ Synthesis of Aluminosilicate Nanofibers in
  Poly(vinyl alcohol) Solution
  K. YAMAMOTO, H. OTSUKA, S.-I. WADA, D. SOHN, A. TAKAHARA
  Soft Matter, Vol. 1, pp372-377 (2005)
  DOI: 10.1039/B508669H

43. Imaging of Charged Micropatterned Monolayer Surfaces by Chemical Force Microscopy
  T. KOGA, H. OTSUKA, A. TAKAHARA
  Bull. Chem. Soc. Jpn., Vol. 78, pp1691-1698 (2005)
  DOI: 10.1246/bcsj.78.1691

42. Reversible Radical Ring-Crossover Polymerization of an Alkoxyamine-Conataining Dynamic
  Covalent Marcocycle
  G. YAMAGUCHI, Y. HIGAKI, H. OTSUKA, A. TAKAHARA
  Macromolecules, Vol. 38, pp6316-6320 (2005)
  DOI: 10.1021/ma0503209

41. Rational Model for Chiral Recognition in a Silica-based Chiral Column: Chiral Recognition of
  N-(3,5-dinitrobenzoyl)phenylglycine- terminated Alkylsilane Monolayer by
  2,2,2-Trifluoro-1-(9-anthryl)ethanol Derivatives by Chemical Force Microscopy
  H. OTSUKA, T. ARIMA, T. KOGA, A. TAKAHARA
  J. Phys. Org. Chem., Vol. 18, pp957-961 (2005)
  DOI: 10.1002/poc.934

40. Molecular Aggregation Structure of Poly(fluoroalkyl acrylate) Thin Films Evaluated by
  Synchrotron-Sourced Grazing-Incidence X-ray Diffraction
  K. HONDA, H. YAKABE, T. KOGA, S. SASAKI, O. SAKATA, H. OTSUKA, A. TAKAHARA
  Chem. Lett., Vol. 34, pp1024-1025 (2005)
  DOI: 10.1246/cl.2005.1024

39. Molecular Aggregation Structure and Surface Properties of Poly(fluoroalkyl acrylate) Thin Films
  K. HONDA, M. MORITA, H. OTSUKA, A. TAKAHARA
  Macromolecules, Vol. 38, pp5699-5705 (2005)
  DOI: 10.1021/ma050394k

38. Macro- and Nanotribological Properties of Organosilane Monolayers Prepared by a Chemical Vapor
  Adsorption Method on Silicon Substrates
  H. ISHIDA, T. KOGA, M. MORITA, H. OTSUKA, A. TAKAHARA
  Tribology Lett., Vol. 19, pp3-8 (2005)
  DOI: 10.1007/s11249-004-4259-9

37. Adsorption of Di-n-butyl Phthalate by Chitosan Beads Modified with Water-soluble Calixarenes
  A. YANAGI, H. OTSUKA, A. TAKAHARA
  Chem. Lett., Vol. 34, pp218-219 (2005)
  DOI: 10.1246/cl.2005.218

36. Macroscopic-Wetting Anisotropy on the Line-Patterned Surface of Fluoroalkylsilane Monolayers
  M. MORITA, T. KOGA, H. OTSUKA, A. TAKAHARA
  Langmuir, Vol. 21, pp911-918 (2005)
  DOI: 10.1021/la0485172

35. Dependence of the Molecular Aggregation State of Octadecylsiloxane Monolayers on Preparation Methods
  T. KOGA, M. MORITA, H. ISHIDA, H. YAKABE, S. SASAKI, O. SAKATA, H. OTSUKA, A. TAKAHARA
  Langmuir, Vol. 21, pp905-910 (2005)
  DOI: 10.1021/la048544s

34. Influence of the Addition of Silsesquioxane on the Dewetting Behavior of Polystyrene Thin Film
  N. HOSAKA, K. TANAKA, H. OTSUKA, A. TAKAHARA
  Composite Interfaces, Vol. 11, pp297-306 (2004)
  DOI: 10.1163/1568554041738157

33. Polystyrene- and Poly(3-vinylpyridine)-Grafted Magnetite Nanoparticles Prepared through
  Surface-Initiated Nitroxide-Mediated Radical Polymerization
  R. MATSUNO, H. OTSUKA, A. TAKAHARA
  Macromolecules, Vol. 37, pp2203-2209 (2004)
  DOI: 10.1021/ma035523g

32. Dynamic Formation of Graft Copolymers via Radical Crossover Reaction of Alkoxyamines
  Y. HIGAKI, H. OTSUKA, A. TAKAHARA
  Macromolecules, Vol. 37, pp1696-1701 (2004)
  DOI: 10.1021/ma035518c

31. Synthesis of Well-Defined Poly(styrene)-b-poly(p-tert-butoxysturene) Multiblock Copolymer from
  Poly(alkoxyamine) Macroinitiator
  Y. HIGAKI, H. OTSUKA, A. TAKAHARA
  Polymer, Vol.44, pp7095-7101 (2003)
  DOI: 10.1016/j.polymer.2003.09.002

30. Thin Silica Film with a Network Structure as Prepared by Surface Sol-Gel Transcription on the
  Poly(styrene-b-4-vinylpyridine) Polymer Film
  N. FUJITA, H. OTSUKA, A. TAKAHARA, S. SHINKAI
  Chem. Lett., Vol. 32, pp352-353 (2003)
  DOI: 10.1246/cl.2003.352

29. Polymer Scrambling: Macromolecular Radical Crossover Reaction between the Main Chains of
  Alkoxyamine-Based Dynamic Covalent Polymers
  H. OTSUKA, K. AOTANI, Y. HIGAKI, A. TAKAHARA
  J. Am. Chem. Soc., Vol. 125, pp4064-4065 (2003)
  DOI: 10.1021/ja0340477

28. Polystyrene-Grafted Magnetite Nanoparticles Prepared through Surface-Initiated Nitroxyl-Mediated Radical
  Polymerization
  R. MATSUNO, K. YAMAMOTO, H. OTSUKA, A. TAKAHARA
  Chem. Mater., Vol. 15, pp3-5 (2003)
  DOI: 10.1021/cm020766t

27. Polyurethane Macroinitiator for Controlled Monomer Insertion of Styrene
  Y. HIGAKI, H. OTSUKA, T. ENDO, A. TAKAHARA
  Macromolecules, Vol. 36, pp1494-1499 (2003)
  DOI: 10.1021/ma021091i

26. Surface Structure and Properties of Multi-Component Micropatterned Organosilane Monolayers Prepared
  by Stepwise Photodecomposition and Chemisorption Process
  T. KOGA, M. MORITA, H. SAKATA, H. OTSUKA, A. TAKAHARA
  Int. J. Nanoscience, Vol. 1, pp419-423 (2002)
  DOI: 10.1142/9789812796714_0008

25. A Dynamic (Reversible) Covalent Polymer: Radical Crossover Behaviour of TEMPO-containing
  Poly(alkoxyamine ester)s
  H. OTSUKA, K. AOTANI, Y. HIGAKI, A. TAKAHARA
  Chem. Commun., Vol. 38, pp2838-2839 (2002)
  DOI: 10.1039/B209193C

24. Fabriaction of Three-Component Micropatterned Organosilane Monolayer by a Stepwise Photolithography
  Process
  K. KOGA, H. OTSUKA, A. TAKAHARA
  Chem. Lett., Vol. 31, pp1196-1197 (2002)
  DOI: 10.1246/cl.2002.1196

23. Pinacol Rearrangement in the Polymer Backbone: Synthesis of Novel Reactive Polymers with Condensed
  Benzopinacol Units in the Main Chain and Their Complete Rearrangement to Poly(benzopinacolone)s
  H. OTSUKA, I. ONOZUKA, T. SHIOYA, T. ENDO
  Macromol. Chem. Phys., Vol. 203, pp1824-1832 (2002)
  DOI: 10.1002/1521-3935(200208)203:12<1824::AID-MACP1824>3.0.CO;2-#

22. Preparation of Novel (Polymer/Inorganic Nanofiber) Composite through Surface Modification of Natural
  Aluminosilicate Nanofiber
  K. YAMAMOTO, H. OTSUKA, S.-I. WADA, A. TAKAHARA
  J. Adhesion, Vol. 78, pp591-602 (2002)
  DOI: 10.1080/00218460213740

21. Surface Modification of Aluminosilicate Nanofiber "Imogolite"
  K. YAMAMOTO, H. OTSUKA, S.-I. WADA, A. TAKAHARA
  Chem. Lett., Vol. 30, pp1162-1163 (2001)
  DOI: 10.1246/cl.2001.1162

20. Novel Reactive Polymers Containing Hemiacetal Ester and Vinyl Moieties: Synthesis and Selective
  Polymerization of 1-Methoxyallyl Methacrylate Derived from Methacrylic Acid and Methoxyallene
  H. OTSUKA, K-i. MORI, T. ENDO
  Macromol. Rapid Commun., Vol. 22, pp1335-1339 (2001)
  DOI: 10.1002/1521-3927(20011101)22:16<1335::AID-MARC1335>3.0.CO;2-I

19. Fine Tuning of Thermal Dissociation Temperature in Copolymers with Hemiacetal Ester Moieties in
  the Side Chain: Effect of Comonomer Component on Dissociation Temperature
  H. OTSUKA, H. FUJIWARA, T. ENDO
  React. Funct. Polym., Vol. 46, pp293-298 (2001)
  DOI: 10.1016/S1381-5148(00)00071-7

18. Pinacol Rearrangement in the Polymer Backbone: New Class of Reactive Polymers with Condensed
  Benzopinacol Units in the Main Chain
  H. OTSUKA, I. ONOZUKA, T. ENDO
  Tetrahedron Lett., Vol. 41, pp1433-1433 (2000)
  DOI: 10.1016/S0040-4039(99)02309-6

17. Synthesis and Controlled Polymerization of p-(1-Methylcyclohexyloxy)styrene and Quick-Response   
  Deblocking Ability of the Obtained Polymer
  H. OTSUKA, T. SATO, T. ENDO
  Macromol. Rapid Commun., Vol. 21, pp48-52 (2000)
  DOI: 10.1002/(SICI)1521-3927(20000101)21:1<48::AID-MARC48>3.0.CO;2-A

16. Thermal Dissociation Behavior of the Polymers with Hemiacetal Esters Moieties in the Side Chain: The
  Effect of Structure on Dissociation Temperature
  H. OTSUKA, H. FUJIWARA, T. ENDO
  J. Polym. Sci., Part A: Polym. Chem., Vol. 37, pp4478-4482 (1999)
  DOI: 10.1002/(SICI)1099-0518(19991215)37:24<4478::AID-POLA2>3.0.CO;2-R

15. Poly(hemiacetal ester)s: New Class of Polymers with Thermal Dissociative Units in the Main Chain
  H. OTSUKA, T. ENDO
  Macromolecules, Vol. 33, pp9059-9061 (1999)
  DOI: 10.1021/ma9909408

14. Guest Inclusion Properties of Calix[6]arene-based Unimolecular Cage Compounds. On Their High
  Cs+ and Ag+ Selectivity and Very Slow Exchange Rates
  H. OTSUKA, Y. SUZUKI, A. IKEDA, K. ARAKI, S. SHINKAI
  Tetrahedron, Vol. 54, pp423-446 (1998)
  DOI: 10.1016/S0040-4020(97)10261-7

13. Thermodynamic Studies of Slow Metal Exchange Processes in Ionophoric Calix[n]arene with
  a Capsule-like Closed Cavity
  Y. SUZUKI, H. OTSUKA, A. IKEDA, S. SHINKAI
  Tetrahedron Lett., Vol. 38, pp421-425 (1997)
  DOI: 10.1016/S0040-4039(96)02315-5

12. Definitive Evidence for Inhibition of Calix[6]arene Ring Inversion Obtained from a 1,3-Xylenyl-Bridged
  Chiral Calix[6]arene
  H. OTSUKA, S. SHINKAI
  J. Am. Chem. Soc., Vol. 118, pp4271-4275 (1996)
  DOI: 10.1021/ja953626b

11. Reinvestigation of Calixarene-Based Artificial-Signaling Acetylcholine Receptors Useful in Neutral
  Aqueous(Water/Methanol) Solution
  K. N. KOH, K. ARAKI, A. IKEDA, H. OTSUKA, S. SHINKAI,
  J. Am. Chem. Soc., Vol. 118, pp755-758 (1996)
  DOI: 10.1021/ja951488k

10. Metal-Induced Conformational Changes in Calix[6]arenes Can Change the Exchange Interaction between
  N-O・ Radicals
  K. ARAKI, R. NAKAMURA, H. OTSUKA, S. SHINKAI
  J. Chem. Soc., Chem. Commun., Vol. 31, pp2121-2122 (1995)
  DOI: 10.1039/C39950002121

9. Syntheses of All Possible Calix[6]arene Derivatives with MeO- and ROCOCH2O- Substituents and Their  
  Metal Binding Properties
  H. OTSUKA, K. ARAKI, S. SHINKAI Tetrahedron, Vol. 51, pp8757-8770 (1995)
  DOI: 10.1016/0040-4020(95)00466-L

8. Syntheses and NMR Spectroscopic Studies of Bridged and Capped Calix[6]arenes: High-Yield Syntheses of
  Unimolecular Caged Compounds from Calix[6]arene
  H. OTSUKA, K. ARAKI, H. MATSUMOTO, T. HARADA, S. SHINKAI
  J. Org. Chem., Vol. 60, pp4862-4867 (1995)
  DOI: 10.1021/jo00120a033

7. Immobilization of the Ring Inversion Motion in Calix[6]arene by a Cap with C3-Symmetry
  K. ARAKI, K. AKAO, H. OTSUKA, K. NAKASHIMA, F. INOKUCHI, S. SHINKAI
  Chem. Lett., Vol. 23, pp1251-1254 (1994)
  DOI: 10.1246/cl.1994.1251  

6. Syntheses of All Possible O-Methylation Products Derivable from
  5,11,17,23,29,35-Hexa-tert-butylcalix[6]arene-37,38,39,40,41,42-hexol
  H. OTSUKA, K. ARAKI, S. SHINKAI
  J. Org. Chem., Vol. 59, pp1542-1547 (1994)
  DOI: 10.1021/jo00085a048

5. Rotation vs. Immobilization Controversy in Calix[6]arenes.Is
  5,11,17,23,29,35-Hexa-tert-butyl-37,39,41-trimethoxy-38,40,42-tris (tert-butoxycarbonylmethoxy) 
  calix[6]arene Really Immobilized?
  H. OTSUKA, K. ARAKI, T. SAKAKI, K. NAKASHIMA, S. SHINKAI
  Tetrahedron Lett., Vol. 34, pp7275-7278 (1993)
  DOI: 10.1016/S0040-4039(00)79307-5  

4. Synthesis and Ion Selectivity of Conformers Derived from Hexahomotrioxacalix[3]arene
  K. ARAKI, M. HASHIMOTO, H. OTSUKA, S. SHINKAI
  J. Org. Chem., Vol. 58, pp5958-5963 (1993)
  DOI: 10.1021/jo00074a021  

3. Conformational Isomerism in and Binding Properties to Alkali Metals and an Ammonium Salt of
  O-Alkylated Homooxacalix[3]arenas
  K. ARAKI, K. INADA, H. OTSUKA, S. SHINKAI
  Tetrahedron, Vol. 49, pp9465-9478 (1993)
  DOI: 10.1016/S0040-4020(01)80216-7  

2. Unequivocal Evidence for the Para-Substituent-through- the-Annulus Rotation in Calix[6]arene
  H. OTSUKA, K. ARAKI, S. SHINKAI
  Chem. Expr., Vol. 8, pp479-482 (1993)

1. Molecular Design of a Calix[6]arene-Based Super-Uranophile with C3-Symmetry. High UO22+ Selectivity
  in Solvent Extraction
  K. ARAKI, N. HASHIMOTO, H. OTSUKA, T. NAGASAKI, S. SHINKAI
  Chem. Lett., Vol. 22, pp829-832 (1993)
  DOI: 10.1246/cl.1993.829


著書 -BOOK-


23. Responsive Dynamic-Covalent Polymers: Self-Healing Polymers through Dynamic Covalent Chemistry
  Wei ZHANG, Yinghua JIN Eds, Dynamic Covalent Chemistry Principles, Reactions and Applications

  K. IMATO, H. OTSUKA
  Wiley, (2017) in press.



22. PET (Poly(ethylene terephthalate)) & PTT (Poly(trimethylene terephthalate))
  S. KOBAYASHI, K. MULLEN Eds, Encyclopedia of Polymeric Nanomaterials

  T. OHISHI, H. OTSUKA
  Springer, pp 1534-1538 (2015).



21. Dynamic Covalent PN (Polymer Nanomaterials)
  S. KOBAYASHI, K. MULLEN Eds, Encyclopedia of Polymeric Nanomaterials

  H. OTSUKA, T. OHISHI
  Springer, pp 636-641 (2015).



20. 動的共有結合を有する化学ゲル
  中野義夫 監修、ゲルテクノロジーハンドブック
  大塚英幸, 後関頼太
  エヌ・ティー・エス, pp202-208 (2014)



19. 組み換え可能な共有結合を有する化学架橋システム
  有光晃二 監修、ラドテック研究会 編集、UV・EB硬化技術の最新応用展開
  大塚英幸, 後関頼太
  シーエムシー出版, pp131-138 (2014).



18. 動的共有結合を利用した修復材料
  編集代表 西 敏夫, 高分子ナノテクノロジーハンドブック -最新ポリマーABC技術を中心として-
  大塚英幸
  エヌ・ティー・エス, pp440-445 (2014).



17. 動的共有結合化学に基づく化学架橋高分子の合成と反応メカニズム
  架橋の反応・構造制御と分析 事例集
  大塚英幸
  技術情報協会, pp9-15 (2014).



16. Self-healing Polymers
  McGraw-Hill Yearbook of Science and Technology 2014
  H. OTSUKA
  McGraw-Hill Education, pp337-340 (2014).



15. 自己修復性化学ゲルの設計
  ゲルの安定化と機能性付与・次世代への応用開発
  大塚英幸
  技術情報協会, pp461-465 (2013).



14. ラジカルプロセスに基づく架橋高分子の合成と反応(角岡正弘、白井正充 監修) 高分子の架橋と分解III
  大塚英幸
  シーエムシー出版 (2012)



13. Polymeric Nanomaterials, (Ed. C. S. S. R. Kumar) Synthesis and Characterization of Polymeric Nanogels
  Y. AMAMOTO, H. OTSUKA, A. TAKAHARA 
  Wiley-VCH (2011)



12. Inorganic and Metallic Nanotubular Materials, (Ed. T. KIJIMA) Structure and Properties of Imogolite
  Nanotubes and Their Application to Polymer Nanocomposites
  H. OTSUKA, A. TAKAHARA     
  Springer (2010)



11. Dynamic Combinatorial Chemistry in Drug Delivery, Bioorganic Chemistry and Materials Science
  (Ed. B. L. MILLER) Dynamic Combinatorial Methods in Materials Science
  T. MAEDA, H. OTSUKA, A. TAKAHARA     
  Wiley (2009)



10. ACS Symposium Series Book: 1024 (Controlled/Living Radical Polymerization: Progress in RAFT, DT,
  NMP & OMRP) (Ed. K. MATYJASZEWSKI) Synthesis and Reaction of Well-defined Copolymers with
  Thermally Exchangeable Dynamic Covalent Bonds in the Side Chains
  H. OTSUKA, Y. AMAMOTO, Y. MATSUDA, T. MAEDA, A. TAKAHARA
  American Chemical Society (2009)  



9. ポリウレタン最新開発動向 -分子設計・配合処方から物理・化学的性質の制御まで 第7章 第1節 高機能化を指向した
  ポリウレタンのナノレベル複合化     
  大塚英幸、高原 淳
  情報機構 (2009)



8. 超分子 サイエンス&テクノロジー(国武豊喜 監修) 第3章 第2節 18. イモゴライトチューブ     
  大塚英幸、高原 淳
  エヌ・ティー・エス (2009)



7. 次世代共役ポリマーの超階層制御と革新機能 (赤木和夫 監修) 第II編
  第4章 無機ナノ構造体を基盤とする共役ポリマーの超階層制御     
  大塚英幸
  シーエムシー出版社 (2009)



6. 熱可塑性エラストマーの材料設計と成形加工 -高性能化と応用技術展開- (山下晋三 監修)
  第2章 生分解性ポリウレタンの高次構造とその特性     
  波多野道子、小林元康、大塚英幸、高原 淳
  技術情報協会 (2007)



5. シルセスキオキサン材料の化学と応用展開(伊藤真樹 監修) 第2章 かご型シルセスキオキサン添加高分子薄膜の
  分子凝集状態と熱的性質     
  穂坂 直、宮本郷太、大塚英幸、高原 淳
  シーエムシー出版社 (2007)



4. 最新 ポリウレタンの設計・改質と高機能化 技術全集 第5章 第1節 ポリウレタンのハイブリッド化     
  大塚英幸, 高原 淳
  技術情報協会 (2007)



3. 接着とはく離のための高分子(松本章一 監修) 第3編 第1章 動的共有結合化学による架橋システム     
  大塚英幸  
  シーエムシー出版社 (2006)



2. モレキュラーインフォーマティクスを拓く分子機能材料(新海征治 編著)
  第2章 精密高分子合成を用いた表面ナノ構造の精密制御     
  高原 淳, 大塚英幸
  日刊工業新聞社 (2006)



1. 反応性高分子の新展開(遠藤 剛 監修) 第8章 弱い共有結合を利用した高分子の合成と反応     
  大塚英幸, 遠藤 剛
  シーエムシー出版社 (2005)




     

総説・解説 -REVIEW-



41. 動的共有結合化学に基づくメカノクロミックエラストマーの設計
  大塚英幸
  日本ゴム協会誌, 90, 195-199 (2017).

40. 自己修復性高分子
  大塚英幸
  高分子, 65, 624-625 (2016).

39. 動的な炭素-炭素結合を利用した高分子新素材を目指して
  大塚英幸, 後関頼太
  繊維学会誌, 72, 332 (2016).

38. 可逆的な炭素-炭素結合に基づく動的共有結合ポリマーゲル
  今任景一, 後関頼太, 大塚英幸
  ネットワークポリマー, 37, 31-40 (2016).

37. 動的共有結合ポリマーの開発 -自在に構造変換できる高分子を目指して-
  大塚英幸, 後関頼太, 今任景一
  化学と教育, 64, 98-101 (2016).

36. 自己修復性高分子の開発動向と構造変換可能な架橋高分子
  大塚英幸
  ペトロテック, 38, 62-66 (2015).

35. 高分子鎖を介して分子を引っ張る!-力で生じる化学反応
  今任景一, 後関頼太, 大塚英幸
  化学, 70, 70-71 (2015).

34. 動的共有結合化学に基づく高分子の自己修復
  今任景一, 大塚英幸
  日本画像学会誌, (2015), 54, 221-228 (2015).

33. 完全自己修復性をもつ高分子ゲルの設計
  今任景一, 大塚英幸
  接着の技術, 35, 16-22, (2015).

32. 動的共有結合化学に基づくアルコキシアミン骨格を有するラジカル反応性高分子の設計
  佐藤知哉, 赤嶺経太, 高原 淳, 大塚英幸
  高分子論文集, 72, 341-353 (2015).
   DOI: 10.1295/koron.2015-0006

31. 進化する高分子設計 -共有結合系における高分子の構造・物性の自在変換-
  大塚英幸
  現代化学, No. 530, 24?28 (2015).

30. 動的共有結合を利用した完全自己修復性ポリマーの開発
  今任景一、後関頼太、大塚英幸
  ファインケミカル, 43, No.12, pp13-20 (2014).

29. 組み換え可能な共有結合を利用する反応性ソフトマテリアルの創製
  大塚英幸
  日本ゴム協会誌, 87, 29-32 (2014).

28. 自己修復性ソフトマテリアルの最前線
  大塚英幸, 大石智之
  金属, 83, 1034-1038 (2013).

27. 自発的な結合組み換え反応を利用する自己修復性化学ゲル
  大塚英幸, 今任景一, 大石智之, 高原 淳
  工業材料, 61, 879-891 (2013).

26. 組み換え可能な共有結合を利用した架橋高分子の構造再編成と自己修復
  大塚英幸
  Rad Tech Japan News Letter, No. 88, pp5-8, (2013).

25. Reorganization of Polymer Structures Based on Dynamic Covalent Chemistry: Polymer Reactions by
  Dynamic Covalent Exchanges of Alkoxyamine Units
  H. OTSUKA
  Polym. J., 45, 879-891 (2013).
  DOI: 10.1038/pj.2013.17

24. ラジカル反応を利用した反応性化学架橋高分子の設計
  大塚英幸,高原淳
  ネットワークポリマー,Vol.33, No.3, pp154-159 (2012)

23. Application of Imogolite Clay Nanotubes in Organic/Inorganic Nanohybrid Materials
  W. MA, W. O. YAH, H. OTSUKA, A. TAKAHARA
  J. Mater. Chem.,22, pp11887-11892 (2012)
  DOI: 10.1039/C2JM31570J

22. 自発的に組み換わる動的共有結合を有する架橋高分子の合成と自己修復挙動
  今任景一,大塚英幸
  日本接着学会誌, Vol.48 No.5 (2012)
  
21. Surface Functionalization of Aluminosilicate Nanotubes with Organic Molecules
  W. MA, W. O. YAH, H. OTSUKA, A. TAKAHARA
  Beilstein Journal of Nanotechnology, Vol. 3, pp82-100 (2012)
  DOI: 10.3762/bjnano.3.10

20. 構造再編成可能な動的共有結合ポリマー
  天本義史, 大塚英幸
  高分子, Vol. 60, pp324-328 (2011)

19. 高分子主鎖のスクランブリング反応
  大塚英幸
  ファインケミカル, Vol. 39, No. 9, pp5-13 (2010)

18. Imogolite Reinforced Nanocomposites: Multifaceted Green Materials
  W. O. YAH, K. YAMAMOTO, N. JIRAVANICHANUN, H. OTSUKA, A. TAKAHARA
  Materials, Vol. 3, pp1709-1745 (2010)
  DOI: 10.3390/ma3031709

17. 動的共有結合に基づく構造変換可能な高分子材料
  大塚英幸
  日本接着学会誌, Vol. 46, pp122-128 (2010)

16. 生分解性ポリウレタンとそのポリ乳酸ブレンドの構造
  白波瀬朋子, 波多野道子, 大塚英幸, 高原 淳
  日本ゴム協会誌, Vol. 82, pp349-355 (2009)

15. 高機能化を指向した異種高分子の主鎖交換反応
  大塚英幸
  ファインケミカル, Vol. 38, No. 8, pp43-52 (2009)

14. Dynamic Covalent Polymers: Reorganizable Polymers with Dynamic Covalent Bonds
  T. MAEDA, H. OTSUKA, A. TAKAHARA
  Prog. Polym. Sci., Vol. 34, pp581-604 (2009)
  DOI: 10.1016/j.progpolymsci.2009.03.001

13. 動的共有結合化学を用いた精密高分子合成と高分子複合化 -自在に構造再編成 可能な高分子の創製を目指して-
  大塚英幸
  化学と工業, Vol. 62, pp626-630 (2009)

12. Preparation of Novel Polymer Hybrids from Imogolite Nanofiber
  K. YAMAMOTO, H. OTSUKA, A. TAKAHARA
  Polym. J., Vol. 39, pp1-15 (2007)
  DOI: 10.1295/polymj.PJ2006128

11. 「動的共有結合化学」に基づく分子構築・集積: 超分子、高分子の新しい合成 プロトコル
   高田十志和, 大塚英幸
  有機合成化学協会誌, Vol. 64, pp194-207 (2006)

10. 架橋高分子の共有結合を光で自在に組み換える
  大塚英幸
  化学,Vol. 61, p60 (2006)

9. 九州大学 先導物質化学研究所 複合分子システム分野
  高原 淳、大塚英幸、小林元康
  成形加工:日本の大学・試験・研究機関の研究 , 138, 37, pp939-945 (2005)

8. ポリマーブラシによる固体表面の精密構造制御
  松野亮介, 小林元康, 大塚英幸, 高原 淳
  化学, Vol. 60, pp70-71 (2005)

7. 動的共有結合を有する反応性高分子の主鎖組み換え反応とナノ複合化への展開
  大塚英幸
  高分子加工, Vol. 54, pp483-488 (2005)

6. 動的共有結合を利用する高分子の構造再編成
  大塚英幸
  高分子, Vol. 53, pp597-597 (2004)

5. Fabrication and Characterization of Multi-component Organosilane Nanofilms
  A. TAKAHARA, H. SAKATA, M. MORITA, T. KOGA, H. OTSUKA
  Composite Interfaces, Vol. 10, pp489-504 (2003)
  DOI: 10.1163/156855403771953713

4. 天然ナノファイバー「イモゴライト」とそのナノハイブリッド化
  高原 淳、大塚英幸、山本和弥、和田信一郎
  工業材料, Vol. 51, pp50-53 (2003)

3. 「弱い共有結合」を基盤とする反応性高分子の設計 -ヘミアセタールエステルの 化学を利用した高分子設計-
  大塚英幸
  日本接着学会誌, Vol. 38, pp27-32 (2002)

2. 1-アルコキシカルボキシレートを基盤とする外部刺激応答性高分子の開発
  大塚英幸
  ネットワークポリマー, Vol. 20, pp177-177 (1999)

1. Stereochemical Control of Calixarenes Useful as Rigid Conformationally Diversiform Platforms for
  Molecular Design
  H. OTSUKA, S. SHINKAI
  Supramol. Sci., Vol. 3, pp189-207 (1997)
  DOI: 10.1016/S0968-5677(96)00038-7


     

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東京工業大学
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